F. Valach, N. N. Hoang, I. Lukeš:
"Structure of Disodiumcis-Bis(iminodiacetato)-cobalt(II) Hexahydrate."
Chem. Pap. 50, (1996) 115-20
Abstract:
The crystal structure
of Na2[Co(Hida)2]×6H2O (Hida = iminodiacetato) contains discrete units[Co(Hida)2]2-, ions Na+, and H2O mols. The pseudo-octahedral coordination ofCo(II) is created by four O atoms (the bond lengthsCo-O are0.202(1), 0.203(1), 0.207(1), and0.210(1) nm) and two N atoms of two Hida ligands (bond lengthsCo-N are0.211(2) and0.214(2) nm). The cations Na+ are pseudo-octahedrally surrounded by four water O atoms and two carboxyl O atoms from the different units[Co(Hida)2]2-. Crystallog. data and at. coordinates are given.