Surface-enhanced Raman Scattering group 

of Prof. Blanka Vlckova

 

 

 

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 Faculty

 Department

 Diploma thesis

 Obecná chemie

 

 

SELECTED PUBLICATIONS:

2018

Slouf, M.; Pilaf, J.; Dybal, J.; Sloufova, I.; Michalkova, D.; Lukesova, M.; Zgadzai, O.; Blank, A.; Filippov, S. K. UV Degradation of Styrene-Butadiene Rubber versus High Density Poly(ethylene) in Marine Conditions Studied by Infrared Spectroscopy, Micro Indentation, and Electron Spin Resonance Imaging. Polym. Degrad. Stab. 2018, 156, 132–143 DOI: 10.1016/j.polymdegradstab.2018.08.005.

Sloufova, I.; Vlckova, B.; Mojzes, P.; Matulkova, I.; Cisarova, I.; Prochazka, M.; Vohlidal, J. Probing the Formation, Structure, and Reactivity of Zn(II), Ag(I), and Fe(II) Complexes with 2,2 `:6 `,2 `’-Terpyridine on Ag Nanoparticles Surfaces by Time Evolution of SERS Spectra, Factor Analysis, and DFT Calculations. J. Phys. Chem. C 2018, 122 (11), 6066–6077 DOI: 10.1021/acs.jpcc.7b12157.

Sutrova, V.; Ivana, S.; Mojzes, P.; Meln, Z.; Kalba, M. Excitation Wavelength Dependence of Combined Surface- and Graphene-Enhanced Raman Scattering Experienced by Free-Base Phthalocyanine Localized on Single-Layer Graphene-Covered Ag Nanoparticle Arrays. 2018 DOI: 10.1021/acs.jpcc.8b06218.

2017

Pilar, J.; Slouf, M.; Michalkova, D.; Sloufova, I.; Vackova, T.; Dybal, J. Pro-Oxidant Activity of Alpha-Tocopherol during Photooxidative Degradation of Polyolefins. ESRI and IR Microspectroscopy Studies. Polym. Degrad. Stab. 2017, 138, 55–71 DOI: 10.1016/j.polymdegradstab.2017.02.008.

Pruskova, M.; Sutrova, V.; Slouf, M.; Vlckova, B.; Vohlidal, J.; Sloufova, I. Arrays of Ag and Au Nanoparticles with Terpyridine- and Thiophene-Based Ligands: Morphology and Optical Responses. Langmuir 2017, 33 (17), 4146–4156 DOI: 10.1021/acs.langmuir.7b00126.

Schwarzova-Peckova, K.; Vosahlova, J.; Barek, J.; Sloufova, I.; Pavlova, E.; Petrak, V.; Zavazalova, J. Influence of Boron Content on the Morphological, Spectral, and Electroanalytical Characteristics of Anodically Oxidized Boron-Doped Diamond Electrodes. Electrochim. Acta 2017, 243, 170–182 DOI: 10.1016/j.electacta.2017.05.006.

Stanek, T.; Dvorak, M.; Almonasy, N.; Nepras, M.; Sloufova, I.; Michl, M. Formation of Planarized Intramolecular Charge-Transfer State in Dichlorotriazinyl-Pyrene Fluorescent Probe: TD-DFT and Resonance Raman Study. Dye. Pigment. 2017, 141, 121–127 DOI: 10.1016/j.dyepig.2017.01.077.

Sutrova, V.; Sloufova, I.; Melnikova, Z.; Kalbac, M.; Pavlova, E.; Vlckova, B. Effect of Ethanethiolate Spacer on Morphology and Optical Responses of Ag Nanoparticle Array-Single Layer Graphene Hybrid Systems. LANGMUIR 2017, 33 (50), 14414–14424 DOI: 10.1021/acs.langmuir.7b03462.

Uhlirova, T.; Mojzes, P.; Melnikova, Z.; Kalbac, M.; Sutrova, V.; Sloufova, I.; Vlckova, B. Raman Excitation Profiles of Hybrid Systems Constituted by Single-Layer Graphene and Free Base Phthalocyanine: Manifestations of Two Mechanisms of Graphene-Enhanced Raman Scattering. J. RAMAN Spectrosc. 2017, 48 (10), 1270–1281 DOI: 10.1002/jrs.5206.

Weis, J. E.; Costa, S.; Frank, O.; Fridrichova, M.; Vlckova, B.; Vejpravova, J.; Kalbac, M. SERS of Isotopically Labeled C-12/C-13 Graphene Bilayer-Gold Nanostructured Film Hybrids: Graphene Layer as Spacer and SERS Probe. J. Phys. Chem. C 2017, 121 (21), 11680–11686 DOI: 10.1021/acs.jpcc.7b02585.

2016

Stenclova, P.; Sichova, K.; Sloufova, I.; Zednik, J.; Vohlidal, J.; Svoboda, J. Alcohol- and Water-Soluble Bis(tpy)quaterthiophenes with Phosphonium Side Groups: New Conjugated Units for Metallo-Supramolecular Polymers. Dalt. Trans. 2016, 45 (3), 12081224 DOI: 10.1039/c5dt04133c.

Faukner, T.; Slany, L.; Sloufova, I.; Vohlidal, J.; Zednik, J. Pi-Conjugated Polyelectrolytes Derived from 2-Ethynylpyridine: The Effect of Quaternization Agent and Reaction Conditions on the Polymer Structure and SERS Characterization of Nanocomposites with Ag-Nanoparticles. Macromol. Res. 2016, 24 (5), 441449 DOI: 10.1007/s13233-016-4062-0.

2015

Stenclova-Blahova, P.; Svoboda, J.; Sloufova, I.; Vohlidal, J. Alcohol-Soluble Bis(tpy)thiophenes: New Building Units for Constitutional Dynamic Conjugated Polyelectrolytes. Phys. Chem. Chem. Phys. 2015, 17 (20), 1374313756 DOI: 10.1039/c5cp01000d.

Kokoskova, M.; Stepanek, M.; Sloufova, I.; Vlckova, B. Steady-State and Time-Resolved Luminescence of Ru(II) Polypyridine Complexes Attached to Ag Nanoparticles: Effect of Chemisorption in Comparison with Electrostatic Bonding. Spectrochim. ACTA PART A-MOLECULAR Biomol. Spectrosc. 2015, 150, 657663 DOI: 10.1016/j.saa.2015.05.088.

Sutrova, V.; Sloufova, I.; Nevoralova, M.; Vlckova, B. SERS microRaman Spectral Probing of Adsorbate-Containing, Liquid-Overlayed Nanosponge Ag Aggregates Assembled from Fractal Aggregates. J. RAMAN Spectrosc. 2015, 46 (6), 559565 DOI: 10.1002/jrs.4690.

Sloufova, I.; Prochazka, M.; Vlckova, B. Identification of Two Ag-2,2 `:6 `,2 `-terpyridine Surface Species on Ag Nanoparticle Surfaces by Excitation Wavelength Dependence of SERS Spectra and Factor Analysis: Evidence for Chemical Mechanism Contribution to SERS of Ag(0)-Tpy. J. RAMAN Spectrosc. 2015, 46 (1), 3946 DOI: 10.1002/jrs.4585.

2014

Philimonenko, V. V; Philimonenko, A. A.; Sloufova, I.; Hruby, M.; Novotny, F.; Halbhuber, Z.; Krivjanska, M.; Nebesarova, J.; Slouf, M.; Hozak, P. Simultaneous Detection of Multiple Targets for Ultrastructural Immunocytochemistry (Vol 141, Pg 229, 2014). Histochem. Cell Biol. 2014, 141 (3), 241 DOI: 10.1007/s00418-014-1196-z.

Blahova, P.; Zednik, J.; Sloufova, I.; Vohlidal, J.; Svoboda, J. Synthesis and Photophysical Properties of New Alpha,omega-Bis(Tpy)Oligothiophenes and Their Metallo-Supramolecular Polymers With Zn2+ Ion Couplers. SOFT Mater. 2014, 12 (2), 214229 DOI: 10.1080/1539445X.2013.858358.

Sloufova, I.; Vlckova, B.; Prochazka, M.; Svoboda, J.; Vohlidal, J. Comparison of SERRS and RRS Excitation Profiles of {[}Fe(tpy)(2)](2+) (Tpy = 2,2:6,2’’-terpyridine) Supported by DFT Calculations: Effect of the Electrostatic Bonding to Chloride-Modified Ag Nanoparticles on Its Vibrational and Electronic Structure. J. RAMAN Spectrosc. 2014, 45 (5), 338348 DOI: 10.1002/jrs.4468.

2013

Kokoskova, M.; Prochazka, M.; Sloufova, I.; Vlckova, B. SERRS Spectra and Excitation Profiles of Ru(II) Polypyridine Complexes Attached to Ag Nanoparticle Aggregates: Structural, Electronic, and Resonance Damping Effects of Chemisorption. J. Phys. Chem. C 2013, 117 (2), 10441052 DOI: 10.1021/jp310579j.

2011

Sisková, K.;  Vlcková, B.; Turpin, P.-Y.,; Thorel, A.;  Prochazka, M.: Laser ablation of silver in aqueous solutions of organic species:  Probing Ag nanoparticle-adsorbate systems evolution by surface-enhanced Raman and surface plasmon extinction spectra, J. Phys. Chem. C 2011, 115, 5404-5412.

2010

Bondarev, D.; Zednik, J.; Sloufova, I.; Sharf, A.; Prochazka, M.; Pfleger, J.; Vohlidal, J. Synthesis and Properties of Cationic Polyelectrolyte with Regioregular Polyalkylthiophene Backbone and Ionic-Liquid Like Side Groups. J. Polym. Sci. Part a-Polymer Chem. 2010 DOI: 10.1002/pola.24085.

Bondarev, D.; Zednik, J.; Sloufova, I.; Sharf, A.; Prochazka, M.; Pfleger, J.; Vohlidal, J. Synthesis and Properties of Cationic Polyelectrolyte with Regioregular Polyalkylthiophene Backbone and Ionic-Liquid Like Side Groups. J. Polym. Sci. PART A-POLYMER Chem. 2010, 48 (14), 30733081 DOI: 10.1002/pola.24085.

2009

Sladkova, M.; Vlckova, B.; Pavel, I.; Siskova, K.; Slouf, M. Surface-enhanced Raman scattering from a single molecularly bridged silver nanoparticle aggregate, J. Mol. Struct. 2009, 924-926, 567-570.

2008

Smejkal, P.; Pfleger, J.; Vlcková, B. Study of laser fragmentation process of silver nanoparticles in aqueous media  Appl. Phys. A: Materials Science and Processing, 2008, 93 (4), 973-976.

Siskova, K.; Vlckova, B.; Turpin, P.-Y.; Thorel, A.; Grosjean, A. Porphyrins as SERRS spectral probes of chemically functionalized Ag nanoparticles, Vibrational Spectroscopy, 2008, 48, 44-52.

Vlcková, B.; Moskovits, M.; Pavel, I.; Siskova, K.; Sladkova, M.; Slouf, M.: Single-molecule surface-enhanced Raman spectroscopy from a molecularly-bridged silver nanoparticle dimer Chem. Phys. Lett. 2008, 455, 131-134.

Sloufova, I.; Siskova, K.; Vlckova, B.; Stepanek, J. SERS-Activating Effect of Chlorides on Borate-Stabilized Silver Nanoparticles: Formation of New Reduced Adsorption Sites and Induced Nanoparticle Fusion. Phys. Chem. Chem. Phys. 2008, 10 (16), 22332242 DOI: 10.1039/b718178g.

Vlckova, B.; Moskovits, M.; Pavel, I.; Siskova, K.; Sladkova, M.; Slouf, M. Single-molecule surface-enhanced Raman spectroscopy from a molecularly-bridged silver nanoparticle dimer Chem. Phys. Lett., 455,2008, 131-134.

2007

Dammer, O.; Vlckova, B.; Slouf, M.; Pfleger, J. Interaction of high-power laser pulses with monodisperse gold particles Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 2007, 140, 138-146.

Vlckova, B.; Pavel, I.; Sladkova, M.; Siskova, K.; Slouf, M. Single molecule SERS: Perspectives of analytical applications J.Mol. Struct., 834-836, 2007, 42-47.

2006

Sladkova, M.; Vlckova, B.; Mojzes, P.; Slouf, M.; Naudin, C.; Le Bourdon, G. Probing strong optical fields in compact aggregates of silver nanoparticles by SERRS of protoporphyrin IX Faraday Discussions, 132, 2006, 121-134

2005

Moskovits, M., Vlckova, B. Adsorbate-induced silver nanoparticle aggregation kinetics J. Phys. Chem. B, 109, 2005, 14755-14758.

Siskova, K., Vlckova, B., Mojzes, P. Spectral detection of J-aggregates of cationic porphyrin and investigation of conditions of their formation, J. Mol. Struct., 744-747, 2005, 265-272.

Prochazka, M., Vlckova, B., Stepanek, J., Turpin, P.-Y. Probing of porphyrin surface chemistry in systems with laser-ablated ag nanoparticle hydrosol: Role of thiosulfate anions Langmuir, 21, 2005, 2956-2962.

2004

Srnova-Sloufova, I; Vlckova, B; Bastl, Z; Hasslett - Bimetallic (Ag)Au nanoparticles prepared by the seed growth method: Two-dimensional assembling, characterization by energy dispersive X-ray analysis, X-ray photoelectron spectroscopy, and surface enhanced Raman spectroscopy, and proposed mechanism of growth, Langmuir, 20, 2004, 3407-3415,

Smejkal, P., Pfleger, J., Siskova, K., Vlckova, B., Dammer, O., Slouf, M. In-situ study of Ag nanoparticle hydrosol optical spectra evolution during laser ablation/fragmentation, Applied Physics A: Materials Science and Processing, 79, 2004, 1307-1309.

2003

Michl, M.; Vlckova, B.; Sloufova, I.; MojzeS, P.:SERS and SERRS spectra of unperturbed hydrophobic molecular and biomolecular species embedded in sulphuric acid-modified silver nanoparticle films, Can. J. Anal. Sci. Spect2003, 48, 6,  46-54.

Smejkal P., SiSkova K.,Vlckova B., Pfleger J., Sloufova I., Slouf  M., MojzeS P. -Characterization and surface-enhanced Raman spectral probing of  silver hydrosols prepared by two-wavelength laser ablation and fragmentation, Spectrochim. Acta Part A 2003, 59, 14, 2321-2329.

2002

Moskovits, M.; Srnova-Sloufova, I.; Vlckova, B.; Bimetallic Ag-Au nanoparticles: extracting meaningful optical constants from the extinction spectrum of surface plasmon extinction spectra, J.Chem.Phys., 116, 2002, 10435-10446

Sloufova-Srnova, I., Vlckova, B.; Two-dimensional assembling of Au nanoparticles mediated by tetrapyridylporphine molecules; Nano Lett. 2, 2002, 121-125

Smejkal, P.; Vlckova, B.; Pfleger, J.; Sloufova, I.; Slouf, M..; Characterization and SERS spectral probing of Ag hydrosols prepared by two-wavelength laser ablation and fragmentation; Acta Universitatis Carolinae, Geologica 46 (1), 2002, 82-83

Prochazka, M., Turpin, P.-Y., Stepanek, J., Vlckova, B. SERRS of free base porphyrin in laser-ablated colloids: Evidence for three different spectral porphyrin forms, J. Raman Spectrosc., 33, 2002, 758-760.

2001

Sloufova, I.; Slouf, M. (Acridine-N)trichlorogold (III), Acta Cryst. C: Cryst. Struct. Commun., 57, 2001, 248-249.

2000

Srnova-Sloufova, I.; Lednický, F.; Gemperle, A.; Gemperlova, J.; Core-shell (Ag)Au Bimetallic Nanoparticles: Analysis of Transmission Electron Microscopy Images, Langmuir, 16, 2000, 9928-9935

Srnova-Sloufova, I.; Vlckova, B.; Snoeck, T.L.; Stufkens, D.J.; Matejka, P., SERS/SERRS Excitation Profiles of Ag-2,2bipyridine Surface Complexes and of [Ru(bpy)3]2+ on Ag Colloidal Surfaces: Manifestations of the CT Resonance Contributions to the Overall Surface Enhancement of Raman Scattering, Inorg.Chem., 39, 2000, 3551-3559.

Vlckova, B., Smejkal, P., Michl, M., Prochazka, M., Mojzes, P., Lednicky, F., Pfleger, J. Surface-enhanced resonance Raman spectroscopy of porphyrin and metalloporphyrin species in systems with Ag nanoparticles and their assemblies J.Inorg. Biochem., 79, 2000, 295-300.

1999

Srnova I., Vlckova B., Nemec I., Slouf M., Stepanek J. - Infrared Microscopy and Surface-Enhanced Raman Scattering of Ag Colloid - 2,2-bipyridine films - J.Mol.Struct., 483, 1999, 213-216.

Michl, M., Vlckova, B., Mojzes, P. Ag colloid-ethanethiol films: Spacer-modified substrates for surface-enhanced resonance Raman scattering spectroscopy of chromophoric molecules Vibrational Spectroscopy, 19 (2), pp. 239-242.

Smejkal, P., Vlckova, B., Prochazka, M., Mojzes, P., Pfleger, J. Testing anionic spacers by SERRS (surface-enhanced resonance Raman scattering) of a cationic free-base porphyrin in systems with laser-ablated Ag colloids Vibrat. Spectrosc., 19, 1999, 243-247.

Michl, M., Vlckova, B., Mojzes, P. SERRS spectra of azo dyes from deposited Ag colloid-azo dye films: Investigating the mechanism of film formation J. Mol. Struct., 482-483, 1999, 217-220.

 Smejkal, P., Vlcková, B., Prochazka, M., Mojzes, P., Pfleger, J. SERRS spectra of cationic free-base porphyrin species adsorbed on laser ablated Ag colloids modified by mercaptoacetate spacers J.Mol.Struct. 482-483, 1999, 225-229.

Vlcková, B., Douketis, C., Moskovits, M., Shalaev, V.M., Markel, V.A. Toward a universal extinction spectrum of self-affine silver colloid clusters: Experiment and simulation J.Chem. Phys., 110, 1999,  8080-8083.

 1998

Srnova I., Prochazka M., Vlckova B., Stepanek J., Maly P. - SERS-Active Systems Prepared from Ag Colloids Laser-ablated in Chemically Modified Aqueous Media -Langmuir, 4666 - 4670, 1998, 14

1997

Srnova I., Vlckova B., Baumruk V. - Enhanced Raman Spectra of 2,2-bipyridine Adsorbed on Aggregated Palladium Colloidal Particles - J.Mol.Struct., 410 - 411, 1997, 201-203

Prochazka M., Stepanek J., Vlckova B., Srnova I., Maly P. - Laser Ablation: Preparation of Chemically Pure Ag Colloids for Surface-enhanced Raman Scattering Spectroscopy - J.Mol.Struct., 410 - 411, 1997, 213-216

Baldwin, J.A., Vlčková, B., Andrews, M.P., Butler, I.S. Surface-enhanced raman scattering of mercaptopyridines and pyrazinamide incorporated in silver colloid-adsorbate films Langmuir, 13, 1997, 3744-3751.

Vlčková, B., Solecká-Čermáková, K., Matějka, P., Baumruk, V. SERS spectroscopy with Ag colloids J.Mol.Struct, 408-4091997 149-154.

Procházka, M., Mojzeš, P., Vlčková, B., Turpin, P.-Y. Surface-enhanced resonance raman scattering from copper(II) 5,10,15,20-tetrakis(1-methyl-4-pyridyl)porphyrin adsorbed on aggregated and nonaggregated silver colloids J. Phys. Chem. B, 101, 1997, 3161-3167.

Vlčková, B., Gu, X.J., Moskovits, M. SERS excitation profiles of phthalazine adsorbed on single colloidal silver aggregates as a function of cluster size  J. Phys. Chem. B, 101, 1997, 1588-1593.

Prochazka, M., Stepanek, J., Vlckova, B., Srnova, I., Maly, P. Laser ablation: Preparation of 'chemically pure' Ag colloids for surface-enhanced Raman scattering spectroscopy J. Mol. Struct., 410-4111997, 213-216.

Procházka, M., Mojzeš, P., Vlčková, B., Turpin, P.-Y. Surface-enhanced resonance Raman scattering of a cationic porphyrin: Determination of surface enhancement factors in the case of molecular resonance excitations J. Mol.Struct., 410-4111997, 209-211.

1996

Solecká-Čermáková, K., Vlčková, B., Lednický, F. Structural characteristics of Ag colloid-adsorbate films determined from transmission electron microscopic images: Fractal dimensions, particle size and spacing distributions, and their relationship to formation and optical responses of the films J. Phys. Chem., 100, 1996, 4954-4960.

Vlčková, B., Gu, X.J., Tsai, D.P., Moskovits, M. A microscopic surface-enhanced Raman study of a single adsorbate-covered colloidal silver aggregate J. Phys. Chem., 100, 1996, 3169-3174.

 Šesták, O., Matějka, P., Vlčková, B. The model of linear aggregate of Ag colloidal particles with variable inter-particle distances Collection of Czechoslovak Chemical Communications, 611996, 59-69.

1994

Vlčková, B., Matějka, P., Van Outersterp, J.W.M., Snoeck, Th.L., Stufkens, D.J. Surface-enhanced Raman scattering spectroscopy of organometallics in systems with aqueous silver colloids Inorg. Chem. 33, 1994, 2132-2136.

 Barnett, S.M., Vlčková, B., Butler, I.S., Kanlgan, T.S. Surface-enhanced Raman scattering spectroscopic study of 17α-ethinylestradiol on silver colloid and in glass-deposited Ag-17α-ethinylestradiol film,  Anal. Chem., 661994, 1762-1765.

1993

Vlčková, B., Barnett, S.M., Kanigan, T., Butler, I.S. Surface enhanced Raman scattering and surface plasmon absorption of glass-deposited silver-2,2′-bipyridine films formed from interfacial silver metal liquid-like films Langmuir, 91993, 3234-3238.

Vlčková, B., Matějka, P., Šimonová, J., Čermáková, K., Pančoška, P., Baumruk, V. Surface-enhanced resonance Raman spectra of free base 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin and its silver complex in systems with silver colloid: Direct adsorption in comparison to adsorption via molecular spacer J.Phys. Chem., 971993, 9719-9729.

1992

Matějka, P., Vlčková, B., Vohlidal, J., Pančoška, P., Baumruk, V. The role of triton X-100 as an adsorbate and a molecular spacer on the surface of silver colloid: A surface-enhanced Raman scattering study J. Phys.Chem., 96, 1992, 1361-1366.

Vlčková, B., Baumruk, V., Mosinger, J. Resonance Raman spectra of bis (2,4-pentanedithionate) palladium (II) complex J.Mol.Struct., 2651992, 9-16.

1991

Vlčková, B., Matějka, P., Pančoška, P., Baumruk, V., Král, V. Surface-enhanced Raman spectra of 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin/silver colloid system: What information about the porphyrin do we obtain? Inorg. Chem., 301991, 4103-4105.

1990

Vlčková, B., Snoeck, Th.L., Stufkens, D.J. Resonance raman excitation profiles of a diamagnetic Cr(III) tris (3,4,5,6-tetrachloro-1,2-benzosemiquinone) complex J.Mol.Struct, 2181990, 7-12.